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Concise Synthesis of Linderaspirone A and Bi‐linderone
Author(s) -
Xiao Fenfen,
Liu Wu,
Wang Yunxia,
Zhang Qing,
Li Xiang,
Hu Xiangdong
Publication year - 2013
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201200184
Subject(s) - chemistry , nanotechnology , materials science
Photogenic : The synthesis of linderaspirone A has been accomplished in only three steps by a Darzens cyclopentenedione synthesis and dioxygen‐assisted photochemical dimerization. Moreover, the thermal isomerization of linderaspirone A into bi‐linderone has been discovered, which may give clues to the biosynthetic pathway for bi‐linderone.