An Inclusion Complex of C 60  with Organosilylated γ‐Cyclodextrin: Drastic Enhancement of Apparent Solubility of C 60  in Nonpolar and Weakly Polar Organic Solvents | Zendy

Takeda Youhei | Zendy; Nagamachi Toshiki | Zendy; Nishikori Katsuaki | Zendy; Minakata Satoshi | Zendy

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An Inclusion Complex of C 60 with Organosilylated γ‐Cyclodextrin: Drastic Enhancement of Apparent Solubility of C 60 in Nonpolar and Weakly Polar Organic Solvents

Author(s) -

Takeda Youhei,

Nagamachi Toshiki,

Nishikori Katsuaki,

Minakata Satoshi

Publication year - 2013

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201200160

Subject(s) - chemistry , solubility , inclusion (mineral) , cyclohexane , cyclodextrin , polar , fullerene , chemical polarity , organic chemistry , chemical engineering , molecule , mineralogy , physics , astronomy , engineering

What a solution! A bi‐capped inclusion complex of C 60 with organosilylated γ‐cyclodextrin that is highly soluble in nonpolar and weakly polar organic solvents, such as CHCl 3 or cyclohexane, was prepared and characterized. The complex facilitates the separation of C 60 from C 70 and selective functionalization of C 60 . Furthermore, fabrication of a thin film of the complex by using a solution technique was demonstrated.

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