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Straightforward and Versatile Synthesis of Fullerooxazoles from C 60 and Carboxamides through Radical Reactions under Mild Conditions
Author(s) -
Takeda Youhei,
Enokijima Satoru,
Nagamachi Toshiki,
Nakayama Kazuhisa,
Minakata Satoshi
Publication year - 2013
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201200114
Subject(s) - chemistry , fullerene , oxazoline , thermostability , combinatorial chemistry , electrochemistry , solubility , organic chemistry , nanotechnology , catalysis , materials science , electrode , enzyme
A direct synthetic method for producing oxazoline‐fused fullerenes, that is, fullerooxazoles, from [60] fullerene and readily available carboxamides by radical pathways has been developed. The method presented allows efficient access to a variety of fullerooxazoles with high functional compatibility under mild reaction conditions. Furthermore, systematic investigation of their properties, such as solubility, thermostability, and electrochemical behavior, was conducted.