Enantiomerically Enriched (4+3) Cycloadducts from Optically Active Epoxy Enolsilanes | Zendy

Lam Sarah | Zendy; Lo Brian | Zendy; Wong WingTak | Zendy; Chiu Pauline | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Enantiomerically Enriched (4+3) Cycloadducts from Optically Active Epoxy Enolsilanes

Author(s) -

Lam Sarah,

Lo Brian,

Wong WingTak,

Chiu Pauline

Publication year - 2012

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201200038

Subject(s) - optically active , chemistry , trifluoromethanesulfonate , enantiomer , epoxy , intermolecular force , bicyclic molecule , organic chemistry , enantiomeric excess , enantioselective synthesis , combinatorial chemistry , stereochemistry , molecule , catalysis

Pure chemistry : Intermolecular (4+3) cycloadditions of optically active epoxy enolsilanes and dienes afford cycloadducts with near complete conservation of enantiomeric purity, in up to 99 % ee. This reaction is a general method to obtain optically active bicyclic compounds for synthesis. TESOTf=triethylsilyl trifluoromethanesulfonate.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research