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Carbon–Halogen Bond Formation by the Reductive Elimination of Pd II Species
Author(s) -
Jiang Xuefeng,
Liu Hui,
Gu Zhenhua
Publication year - 2012
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201200035
Subject(s) - reductive elimination , chemistry , oxidative addition , halogen , halide , halogen bond , palladium , aryl , catalysis , carbon fibers , medicinal chemistry , organic chemistry , alkyl , materials science , composite number , composite material
It is well known that Pd 0 undergoes oxidative addition to organic halides, especially aryl or vinyl halides. In the contrast, the formation of organic halides by reductive elimination of RPd II X (X=halogen) has been mostly ignored until very recently. This Focus Review discusses recent developments in palladium‐catalyzed carbon–halogen bond formation by the reductive elimination of RPd II X. These new developments have enriched the scope of palladium‐catalyzed reactions, and provide a new way to construct carbon–halogen bonds.