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Cavitation reactors: Efficiency assessment using a model reaction
Author(s) -
Gogate Parag R.,
Shirgaonkar Irfan Z.,
Sivakumar M.,
Senthilkumar P.,
Vichare Nilesh P.,
Pandit Aniruddha B.
Publication year - 2001
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690471115
Subject(s) - cavitation , chemistry , chemical reaction , aqueous solution , mechanics , decomposition , materials science , process engineering , engineering , organic chemistry , physics
Acoustic and hydrodynamic cavitation can be used for a variety of applications ranging from biological applications such as cell disruption to chemical reactions such as oxidation of organic pollutants in aqueous effluents, including biorefractory toxic chemicals. Different equipment used for cavitational effects was compared based on a model reaction (decomposition of potassium iodide resulting into iodine liberation). A correlation was developed for the prediction of the cavitational yield in terms of the cavity collapse pressure. This correlation, when used with earlier correlations for the pressure amplitude generated during the violent collapse of cavities, will help design engineers to choose particular equipment, operating conditions, and geometric parameters to achieve a desired chemical change. The developed equation relating the macroscopic reaction rates with the collapse pressure is the first of its kind reported in the literature. Pilot‐plant‐scale hydrodynamic cavitation orifice plate setup is most energy‐efficient, with significantly higher cavitational yields for the model reaction.