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Use of hydration and dissociation chemistries with the electrolyte–NRTL model
Author(s) -
Chen ChauChyun,
Mathias Paul M.,
Orbey Hasan
Publication year - 1999
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690450719
Subject(s) - non random two liquid model , electrolyte , extrapolation , chemistry , thermodynamics , dissociation (chemistry) , activity coefficient , mathematics , physics , electrode , aqueous solution , mathematical analysis
Sound theoretical understanding and accurate mathematical representation of electrolyte solution nonideality were the subject of extensive research efforts for decades. It is demonstrated that these goals can be achieved by incorporation of hydration and partial dissociation chemistries with the semi‐empirical electrolyte NRTL model. The resulting model provides a comprehensive thermodynamic framework for accurate correlation and reliable extrapolation of electrolyte solution nonideality over the entire concentration range.