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Measuring induction period for calcium sulfate dihydrate precipitation
Author(s) -
Lancia Amedeo,
Musmarra Dino,
Prisciandaro Marina
Publication year - 1999
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690450218
Subject(s) - induction period , period (music) , precipitation , sulfate , calcium , chemistry , environmental science , mineralogy , meteorology , geography , organic chemistry , physics , catalysis , acoustics
Homogeneous nucleation of CaSO 4 ·2H 2 O (gypsum) based on an optical diagnostic technique was studied within a supersaturation range of 1–4 at 25–90°C. The experiments were carried out using an experimental apparatus consisting of a batch crystallizer with the related measurement devices. Signals of scattered and transmitted light coming from a He–Ne laser source were analyzed to measure the induction period (t ind ), that is, the time delay necessary for homogeneous nucleation to take place. As expected from theory, it was found that t ind decreases when either temperature or supersaturation increase; from the dependence of t ind on supersaturation, it was possible to distinguish between the mechanisms of homogeneous and heterogeneous nucleation. From the experimental data relative to homogeneous nucleation, the interfacial tension (γ s ) between CaSO 4 ·2H 2 O and the surrounding aqueous solution and the activation energy (E att ) for CaSO 4 ·2H 2 O crystallization were evaluated. In particular, the dependence of t ind on temperature made it possible to evaluate E att at 30 kJ/mol and the dependence of t ind on supersaturation offered the value of γ s to be about 37 mJ/m 2 , which does not vary with temperature in the interval explored.