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Surface tension prediction for pure fluids
Author(s) -
Escobedo Joel,
Mansoori G. Ali
Publication year - 1996
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690420523
Subject(s) - surface tension , materials science , surface (topology) , thermodynamics , mechanics , composite material , mathematics , physics , geometry
For the surface tension of organic compounds, σ = [ ·(ρ l ‐ ρ v )] 4 is proposed where = 0 ·(1 − T r ) 0.37 ·T r ·exp(0.30066/T r + 0.86442·T r 9 ). ρ l and ρ v are molar densities of liquid and vapor, respectively, T r = T/T c , and 0 is a temperature‐independent, compound‐dependent constant similar to Sugden's parachor. This new expression, derived from statistical‐mechanics, represents the experimental surface tension data of 94 different organic compounds within 1.05 AAD%. We also propose 0 = 39.6431· [0.22217 − 2.91042 × 10 −3 ·(ℛ*/T br 2 )·T c 13/12 /P c 5/6 ] as a corresponding‐states expression to correlate the temperature‐independent parameter 0 for various compounds. Here, ℛ* = ℛ m,ref , ℛ m is the molar refraction, ℛ m,ref is the molar refraction of the reference fluid (methane), and T br is the reduced normal boiling point. When this generalized expression is used, surface tensions for all 94 compounds can be predicted within 2.57 AAD% at all temperatures investigated.