Heat capacity and heat of dissociation of methane hydrates | Zendy

Rueff Roger M. | Zendy; Dendy Sloan E. | Zendy; Yesavage Victor F. | Zendy

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Heat capacity and heat of dissociation of methane hydrates

Author(s) -

Rueff Roger M.,

Dendy Sloan E.,

Yesavage Victor F.

Publication year - 1988

Publication title -

aiche journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.958

H-Index - 167

eISSN - 1547-5905

pISSN - 0001-1541

DOI - 10.1002/aic.690340908

Subject(s) - heat capacity , methane , clathrate hydrate , hydrate , thermodynamics , chemistry , calorimeter (particle physics) , differential scanning calorimetry , dissociation (chemistry) , organic chemistry , physics , detector , electrical engineering , engineering

The objective of this study was to determine the heat capacity and heat of dissociation of methane hydrates. A technique has been devised which circumvents the two major problems encountered in measuring gas hydrate heat capacity: the need to impose a mechanical pressure during the measurement and the need to have an absolutely pure hydrate sample. The technique was shown to be successful utilizing high‐pressure, constant‐volume cells in a differential scanning calorimeter.

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