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Carbochlorination of metal oxides with phosgene
Author(s) -
Adelman D. J.,
Burnet George
Publication year - 1987
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690330109
Subject(s) - phosgene , metal , chemistry , chemical engineering , engineering , organic chemistry
Kinetics of the carbochlorination with phosgene of an alumina‐silica material are reported for a temperature range of 723 to 1,023 K and a phosgene partial pressure range of 4 to 90 kPa. The oxides react in a constant ratio over most of the conversion range and the grain model accurately predicts conversion as a function of time.