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A statistical mechanical model for adsorption and flow of pure and mixed gases in porous media with homogeneous surfaces. Part I: Theoretical development
Author(s) -
Lee C. S.,
O'Connell J. P.
Publication year - 1986
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690320111
Subject(s) - adsorption , homogeneous , porous medium , porosity , diffusion , thermodynamics , surface diffusion , development (topology) , surface (topology) , chemical engineering , materials science , flow (mathematics) , chemistry , chemical physics , mechanics , composite material , physics , geometry , mathematics , engineering , mathematical analysis
A unified statistical mechanical treatment is developed for adsorption and surface diffusion on homogeneous surfaces. Using molecular parameters, the model accounts for all physical effects of adsorbent‐adsorbate, adsorbate‐adsorbate, and adsorbate‐gas interactions at submonolayer coverages.