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Kinetics of CO oxidation over Co 3 O 4 /γ‐Al 2 O 3 . Part III: Mechanism
Author(s) -
Perti Deepak,
Kabel R. L.,
McCarthy G. J.
Publication year - 1985
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690310905
Subject(s) - catalysis , kinetics , oxide , oxidation state , adsorption , chemistry , variety (cybernetics) , redox , metal , chemical kinetics , reaction mechanism , inorganic chemistry , physics , organic chemistry , computer science , quantum mechanics , artificial intelligence
Interpretations of a variety of transient experiments are combined with information from the literature to reveal the roles played by the Co 3 O 4 catalyst surface and adsorbed species. The reaction path depends on the oxidation state of the catalyst. A rather coherent picture of oxidation‐reduction catalysis by a metal oxide is obtained.