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Experimental measurement of the thermal stability criteria for the low pressure methanol synthesis
Author(s) -
Berty J. M.,
Lenczyk J. P.,
Shah S. M.
Publication year - 1982
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690280605
Subject(s) - stability (learning theory) , methanol , thermal stability , work (physics) , thermodynamics , chemistry , thermal , kinetics , basis (linear algebra) , scale (ratio) , mathematics , control theory (sociology) , mechanics , computer science , organic chemistry , physics , classical mechanics , geometry , control (management) , quantum mechanics , machine learning , artificial intelligence
The mathematical basis was derived for the experimental measurement of the “Slope Condition” and of the “Dynamic Condition” of the thermal stability criteria in a laboratory‐scale internal recycle reactor. This work also resulted in clearer interpretations and simpler expressions for the two stability criteria. The method was experimentally demonstrated on the example of the low pressure methanol synthesis. Only seven experiments were needed to evaluate the stability criteria of this reaction for which the kinetics is unknown.

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