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A study of the volumetric and phase behavior of binary systems. Part I. Critical properties of propane‐perfluorocyclobutane mixtures
Author(s) -
Barber J. R.,
Kay W. B.,
Teja A. S.
Publication year - 1982
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690280119
Subject(s) - propane , critical point (mathematics) , thermodynamics , binary number , azeotrope , binodal , materials science , phase diagram , phase (matter) , chemistry , mathematics , physics , chromatography , organic chemistry , mathematical analysis , arithmetic , distillation
The volumetric and phase behavior of propane‐perfluorocyclobutane mixtures has been determined in the critical region. This system exhibits a minimum temperature point in its critical locus curve and forms a positive critical azeotrope. The measured critical points in this system and their correlation using an extended corresponding states principle are reported in this paper.

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