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Solubility extrema in solid‐fluid equilibria
Author(s) -
Kurnik R. T.,
Reid R. C.
Publication year - 1981
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690270528
Subject(s) - solubility , thermodynamics , maxima and minima , naphthalene , bar (unit) , ethylene , chemistry , materials science , mathematics , organic chemistry , physics , mathematical analysis , meteorology , catalysis
Experimental data and theory both support the contention that there is a maximum solubility in solid‐fluid equilibria. An example system, naphthalene‐ethylene, at temperatures between the upper and lower critical end points and at pressures from 1 to 1000 bar is considered. There is also a solubility minimum in this system.