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Distribution equilibrium between a bulk phase and small pores
Author(s) -
Glandt E. D.
Publication year - 1981
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690270109
Subject(s) - virial coefficient , thermodynamics , phase (matter) , hard spheres , constant (computer programming) , distribution (mathematics) , series (stratigraphy) , spheres , henry's law , materials science , chemistry , statistical physics , physics , mathematics , geology , mathematical analysis , organic chemistry , paleontology , astronomy , solubility , computer science , programming language
The pore‐bulk distribution coefficient K for a solute species is calculated by modelling the solute molecules as hard spheres. K is expanded in a virial‐type series in powers of the bulk‐phase concentration. The leading term is the Henry's law constant. The next two coefficients are reported for three pore shapes.