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An equation of state for polyatomic fluids
Author(s) -
Mohanty Kishore K.,
Ted Davis H.
Publication year - 1979
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690250417
Subject(s) - equation of state , van der waals force , van der waals equation , polyatomic ion , physics , classical mechanics , thermodynamics , chemistry , quantum mechanics , molecule
An equation of state has been developed for convex nonspherical particles with nonpolar and multipolar forces. The effects of nonsphericity and multipolarity on phase behavior are characterized by a geometric shape parameter and an energy fluctuation parameter, respectively. The equation performs for real fluids better than the Van der Waals equation and as well as the Redlich‐Kwong and Peng‐Robinson equations.

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