Premium
A new thermodynamic representation of binary electrolyte solutions nonideality in the whole range of concentrations
Author(s) -
Cruz JoseLuis,
Re Henri
Publication year - 1978
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690240508
Subject(s) - activity coefficient , chemistry , osmotic coefficient , electrolyte , thermodynamics , dilution , non random two liquid model , isothermal process , strong electrolyte , aqueous solution , solvent , debye–hückel equation , hydrochloric acid , inorganic chemistry , organic chemistry , electrode , physics
A system of equations based on the ionic atmosphere theory of Debye and Huckel, Born model contribution, and local compositions of the nonrandom two‐liquid (NRTL) model is developed to represent isothermal activity coefficients, in the whole range of concentrations, for solutions in an undissociated solvent of a partially or completely dissociated electrolyte. The physical constants and the four adjustable parameters necessary to represent the osmotic coefficient, for fifteen strong aqueous electrolytic solutions, are given at 298.15°K and atmospheric pressure. Vapor‐liquid equilibrium, for the hydrochloric acid‐water system at 298.15°K, is represented for acid compositions ranging from infinite dilution to 18 M using a known dissociation constant and six parameters.