Adsorption and desorption of particles and their chromatographic separation | Zendy

Ruckenstein Eli | Zendy; Prieve Dennis C. | Zendy

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Adsorption and desorption of particles and their chromatographic separation

Author(s) -

Ruckenstein Eli,

Prieve Dennis C.

Publication year - 1976

Publication title -

aiche journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.958

H-Index - 167

eISSN - 1547-5905

pISSN - 0001-1541

DOI - 10.1002/aic.690220209

Subject(s) - adsorption , desorption , van der waals force , chemistry , diffusion , chromatography , particle (ecology) , separation (statistics) , chemical physics , chemical engineering , thermodynamics , molecule , organic chemistry , physics , oceanography , machine learning , computer science , geology , engineering

Rates of adsorption/desorption are calculated by considering Born, double‐layer, and van der Waals forces. Conditions exist where rates are highly sensitive to particle size, shape, and chemical constitution because diffusion over a potential barrier controls. On this basis, a new separation technique, called potential‐barrier chromatography, is suggested.

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