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Method of evaluation and reduction of vapor‐liquid equilibrium data of binary mixtures
Author(s) -
Fabries JeanFrançois,
Re Henri
Publication year - 1975
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690210414
Subject(s) - binary number , thermodynamics , vapor–liquid equilibrium , binary data , chemistry , reduction (mathematics) , experimental data , mathematics , statistics , physics , geometry , arithmetic
A new method to reduce vapor‐liquid equilibrium data of binary mixtures and to evaluate a thermodynamic model is presented. It is based on the principle of maximum likelihood. Deviations between all measured and predicted quantities are calculated and confidence limits in model parameters are evaluated from the given estimates of experimental errors. Many examples illustrate the practical applications of the method.