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Compressibility factor of polar fluids in the gaseous and liquid regions
Author(s) -
Stipp Gordon K.,
Bai S. D.,
Stiel Leonard I.
Publication year - 1973
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690190621
Subject(s) - acentric factor , polar , compressibility factor , thermodynamics , compressibility , chemistry , physics , astronomy
The tables of Pitzer et al. for the compressibility factor of nonpolar substances have been extended to polar fluids for the gaseous and liquid regions for reduced temperatures from 0.8 to 1.15 and reduced pressures from 0.2 to 6.0. Available experimental PVT data for polar fluids were related to the acentric factor and fourth parameter at constant reduced temperature and pressure by a quadratic least squares procedure. The resulting relationships reproduced the data utilized with good accuracy for the entire region considered.