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Mass transfer into dilute polymeric solutions
Author(s) -
Wasan D. T.,
Lynch M. A.,
Chad K. J.,
Srinivasan N.
Publication year - 1972
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690180508
Subject(s) - mass transfer coefficient , chemistry , mass transfer , polymer , shear thinning , aqueous solution , thermal diffusivity , solubility , shear rate , viscosity , oxygen , thermodynamics , laminar flow , diffusion , rheology , chemical engineering , chromatography , organic chemistry , physics , engineering
Mass transfer into dilute polymeric solutions was studied by using a short wetted‐wall column. Oxygen was absorbed into thin films of water and aqueous polymeric solutions. The polymer systems studied included dilute solutions of carboxymethylcellulose, polyethylene oxide, Carbopol, and Cyanamer. All of the above systems were moderately non‐Newtonian with power law indexes less than unity. Methocel (a Newtonian fluid with a power law index of one) was also studied. The flow of liquid films was well within the laminar flow regime. The rheological properties of these solutions as well as equilibrium solubility of oxygen in these solutions were determined. In all of the polymer systems studied except Polyox the equilibrium so ubility of oxygen decreased with an increase in polymer concentration. In Polyox solutions, however, the equilibrium solubility of oxygen increased with an increase in polymer concentration. For all of the systems investigated (including Polyox) the mass transfer coefficient for absorption of oxygen at a given flow rate decreased with an increase in polymer concentration. The mass transfer coefficient was highest for water at all flow rates. The diffusivity of oxygen in all of the systems considered except Polyox was lower than that in water. This was attributed to the increased viscosity of the polymeric solutions. The diffusivity of oxygen in Polyox solutions was higher than it was in water. This was found to be due to the complex chemical reactions which occur in this system. In all of the pseudoplastic systems studied the diffusivity of oxygen increased with increasing wall shear rate (decreasing viscosity).