Prediction of breakthrough curves in packed beds: I. Applicability of single parameter models

Conditions under which simplified, single parameter models may be used to predict breakthrough curves in linear, packed bed adsorbers and thermal regenerators are examined with reference, in particular, to earlier conditions proposed by Handley and Heggs and by Babcock and co‐workers. It is found that for high values of heat capacity ratio the Schumann model provides a satisfactory description of packed bed dynamics where fluids axial dispersion and solids conduction effects are lumped into a single parameter the curve spread parameter σ*. For low values of heat capacity ratio, the equivalent conductivity model of Babcock and co‐workers should provide a more accurate description. The value of the Biot number Bi was found to provide the sole criterion for estimating the relative importance of the internal solids conduction. Empirical correlations are presented which allow rapid estimates of breakthrough curves to be made from the curve spread parameter and which facilitate analysis of experimental data from breakthrough curve experiments.