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Kinetics of slow thermal chlorination of hydrogen in nickel tubular flow reactors
Author(s) -
Bernstein Leonard S.,
Albright Lyle F.
Publication year - 1972
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690180126
Subject(s) - nickel , hydrogen , chemistry , chlorine , kinetics , thermal , thermodynamics , chemical kinetics , organic chemistry , physics , quantum mechanics
The first reliable kinetic data and correlations yet reported were obtained for the thermal reaction of gaseous chlorine and hydrogen over a wide range of operationg conditions. Earlier data had been obtained in reactors that result in irreproducible data. The results of the present investigation clarify the reaction sequence that consists of both gas‐phase and surface reactions.