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Reaction equilibrium of real fluid mixtures
Author(s) -
Gaggioli Richard A.,
Nierode Dale E.
Publication year - 1971
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690170133
Subject(s) - homogeneous , thermodynamics , ideal (ethics) , ideal gas , real gas , ammonia , chemistry , equation of state , mathematics , statistical physics , physics , organic chemistry , philosophy , epistemology
A theoretical approach to equilibrium calculations for homogeneous real fluid mixtures is presented. The overall approach is developed for, although not theoretically restricted to, a corresponding states equation of state, z ( T r , p r ). The method is applied to the gaseous ammonia synthesis data of Larson and Dodge. Excellent agreement was attained with the data. Quite significant improvement was observed over the ideal gas and ideal solutions approximations.