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Role of concentration level of the nondiffusing species in turbulent gas phase mass transfer at ordinary mass transfer rates
Author(s) -
Wasan Darshanlal T.,
Wilke Charles R.
Publication year - 1968
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690140408
Subject(s) - mass transfer , schmidt number , mass transfer coefficient , turbulence , thermodynamics , chemistry , diffusion , sherwood number , reynolds number , churchill–bernstein equation , mechanics , momentum transfer , physics , optics , nusselt number , scattering
Numerical solutions to the diffusion‐convection equations are obtained with a digital computer to establish the role of concentration level of the nondiffusing species in nonequivolume diffusion in fully developed turbulent flow of gases in pipes. Results indicate that under ordinary mass transfer rates for a system at constant Schmidt and Reynolds numbers product of the gas‐phase mass transfer coefficient and the log mean partial pressure of the nondiffusing gas is nearly constant both in the mass transfer entry region and in the fully developed region. These results are compared with the experimental data on vaporization and absorption processes. We show that the effect of the mass transfer section length on the rate of turbulent mass transfer is quite significant. Furthermore, the results of the diffusion—convection analysis are in better agreement with experimental data for sections of finite length than results calculated from the momentum‐mass transfer analogy. The two methods agree in the limit for tubes of infinite length.