Liquid‐liquid phase behavior of binary solutions at elevated pressures | Zendy

Winnick Jack | Zendy; Powers J. E. | Zendy

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Liquid‐liquid phase behavior of binary solutions at elevated pressures

Author(s) -

Winnick Jack,

Powers J. E.

Publication year - 1966

Publication title -

aiche journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.958

H-Index - 167

eISSN - 1547-5905

pISSN - 0001-1541

DOI - 10.1002/aic.690120314

Subject(s) - isothermal process , thermodynamics , chemistry , binary number , phase (matter) , liquid phase , acetone , vapor pressure , chromatography , analytical chemistry (journal) , organic chemistry , physics , arithmetic , mathematics

Isothermal pressure elevation can sometimes cause liquid‐liquid phase separation of binary liquid mixtures. A quantitative thermodynamic analysis of this effect is made and applied to the system acetone–carbon disulfide at 0°C. with the use of available P‐V‐T‐X data and vapor pressure data at low pressure. Visual observations of the phase separations at pressures up to 80,000 lb./sq.in. were used to compare with the results of the thermodynamic analysis.

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