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Effective binary diffusion coefficients in mixed solvents
Author(s) -
Tang Y. P.,
Himmelblau D. M.
Publication year - 1965
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690110114
Subject(s) - diffusion , benzene , toluene , chemistry , thermodynamics , solvent , binary number , effective diffusion coefficient , carbon tetrachloride , organic chemistry , mathematics , medicine , physics , arithmetic , radiology , magnetic resonance imaging
The diffusion of carbon dioxide through ethanol‐water, benzene toluene, and carbon tetrachloride benzene was studied over the entire range of compositions for the solvent pairs. The results were interpreted in terms of an effective binary diffusion coefficient. Two semiempirical correlations were derived with the aid of absolute reaction rate theory to predict the effective binary diffusion coefficient from the binary diffusion coefficients of the solute in the individual pure solvents. These equations, although only crude approximations, reproduced the experimental data for six diffusion systems fairly well, including the highly nonideal solvent mixture ethanol‐water.