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Prediction of vapor‐liquid equilibria of binary systems: Part I. Effect of pressure on vapor‐liquid equilibria of binary systems
Author(s) -
Tamura Mikio,
Nagata Isamu
Publication year - 1962
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690080206
Subject(s) - binary number , thermodynamics , chemistry , vapor–liquid equilibrium , binary system , atmospheric pressure , vapor pressure , experimental data , aqueous solution , chromatography , organic chemistry , meteorology , mathematics , physics , statistics , arithmetic
This paper presents an empirical method for the prediction of vapor‐liquid equilibrium data of a binary system at various pressures on the basis of equilibrium data near atmospheric pressure. The proposed method is tested for six hydrocarbon systems and one aqueous system. The calculated results are in good agreement with the experimental data.