Premium
Kinetic data from nonisothermal experiments: Thermal decomposition of ethane, ethylene, and acetylene
Author(s) -
Towell Gordon D.,
Martin Joseph J.
Publication year - 1961
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690070432
Subject(s) - kinetic energy , thermodynamics , isothermal process , acetylene , chemistry , millisecond , ethylene , atmospheric temperature range , thermal decomposition , activation energy , decomposition , dilution , physics , organic chemistry , quantum mechanics , astronomy , catalysis
A rigorous method was developed to account for nonuniform temperature distributions in the analysis of kinetic data. The rate constants cannot be determined directly since they are functions of temperature, so equations were derived and solutions developed for the substantially temperature independent kinetic parameters, activation energy, and pre‐exponential factor. A digital computer was used to evaluate numerically various integrals involved in the solution of the equations. The method developed here will be useful in all laboratory kinetic studies where limitations of heat transfer do not permit an isothermal experiment and in the analysis of kinetic data obtained from commerical or pilot plant units where the temperature distribution is nearly always nonuniform. Kinetic studies were made of the thermal decompositions of ethane, ethylene, and acetylene, all of which are high temperature fast reactions. The experimental conditions covered highly nonuniform temperature distributions with peaks from 730° to 1,330°C., a total pressure of 1 atm., varying amounts of nitrogen dilution, and residence times in the millisecond range.