Catalytic decomposition of nitric oxide | Zendy

Sakaida R. R. | Zendy; Rinker R. G. | Zendy; Wang Y. L. | Zendy; Corcoran W. H. | Zendy

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Catalytic decomposition of nitric oxide

Author(s) -

Sakaida R. R.,

Rinker R. G.,

Wang Y. L.,

Corcoran W. H.

Publication year - 1961

Publication title -

aiche journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.958

H-Index - 167

eISSN - 1547-5905

pISSN - 0001-1541

DOI - 10.1002/aic.690070425

Subject(s) - catalysis , decomposition , pellets , nitric oxide , volume (thermodynamics) , chemistry , oxide , platinum , nitrogen , volumetric flow rate , nickel oxide , inorganic chemistry , chemical engineering , materials science , thermodynamics , composite material , organic chemistry , physics , engineering

Catalytic decomposition of nitric oxide at a concentration of 0.404 and 0.432% by volume in nitrogen was studied in a tubular flow reactor. The packing consisted of alumina pellets impregnated with 0.1% by weight of platinum oxide and 3.0% by weight of nickel oxide. Tests were conducted at pressures of 1 to 15 atm. and temperatures from 800° to 1,000°F. A rate equation correlating the data as a function of temperature, pressure, and compositions was developed. A reaction mechanism compatible with the rate equation is proposed.

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