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Compressibility and vapor pressure of methyl borate
Author(s) -
Griskey Richard G.,
Gorgas Walter E.,
Canjar Lawrence N.
Publication year - 1960
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.690060124
Subject(s) - vapor pressure , volume (thermodynamics) , thermodynamics , equation of state , boron , chemistry , compressibility , organic chemistry , physics
Pressure‐volume‐temperature measurements have been made on methyl borate over the temperature range of 2257deg; to 300°C. and pressures of 30 to 200 atm. in a variable volume P ‐ V ‐ T bomb. Vapor‐pressure measurements from 180°C. to the critical point have also been made with the same apparatus. The vapor‐pressure data are presented in the form of the Antoine equation, and the P ‐ V ‐ T data together with the vapor‐pressure data have been fitted to the Benedict‐Webb‐Rubin equation of state.