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Core‐shell structured HZSM ‐5@ mesoSiO 2 catalysts with tunable shell thickness for efficient n ‐butane catalytic cracking
Author(s) -
Yang Qingxin,
Li Yuming,
Chen Zhentao,
Hu Linxie,
Li Zhenye,
Wang Yajun,
Zhao Zhen,
Xu Chunming,
Jiang Guiyuan
Publication year - 2021
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.17130
Subject(s) - butane , catalysis , fluid catalytic cracking , diffusion , reaction rate constant , chemistry , cracking , shell (structure) , chemical engineering , analytical chemistry (journal) , materials science , kinetics , chromatography , organic chemistry , thermodynamics , composite material , physics , quantum mechanics , engineering
A series of core‐shell HZSM‐5@mesoSiO 2 with tunable shell thickness from 10 to 70 nm was prepared and studied for n ‐butane catalytic cracking. With introducing of SiO 2 shell, the catalytic performance of HZSM‐5@mesoSiO 2 was largely enhanced, and n ‐butane conversion rate per Al site reached to 2.43 min −1 over HZSM‐5@mesoSiO 2 (1:4) at 675°C which is nearly twice to that of HZSM‐5 (1.34 min −1 ). The diffusion property of n ‐butane over as‐prepared sample was quantified by measuring the diffusional time constants using zero length column chromatography technique (ZLC). Combining with chemical reaction kinetic analysis, the quantitative relationship between diffusion property and catalytic performance was effectively established for the first time in n ‐butane catalytic cracking. Positive linear correlation between diffusional time constant ( D / R 2 ) and n ‐butane conversion rate per Al site could be found, which confirms that diffusion enhancement by hierarchical structure is an effective strategy to improve the activity of HZSM‐5 in catalytic cracking.