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Laboratory‐scale liquefiers for natural gas: A design and assessment study
Author(s) -
Preetzmann Nils,
Eckmann Philipp,
Veen Adriaan M. H.,
Li Jianrong,
Richter Markus
Publication year - 2021
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.17128
Subject(s) - liquefaction , calibration , liquefied natural gas , supercritical fluid , condensation , natural gas , chemistry , process engineering , fraction (chemistry) , sample (material) , thermodynamics , chromatography , engineering , organic chemistry , physics , statistics , mathematics
Abstract Exact knowledge of natural gas composition is essential in custody transfer to determine the energy content of the delivery. However, for liquefied natural gas (LNG), a reliable composition determination is difficult. Here, we describe the design of a laboratory‐scale reference liquefier that enables the validation and calibration of optical spectroscopy sensors by providing them with a sample of metrologically traceable composition. Hence, it is crucial to avoid fractionation of the sample during liquefaction. This is realized by supercritical liquefaction of a reference gas mixture in conjunction with a special vapor–liquid‐equilibrium (VLE) cell. As this is a demanding high‐pressure application, low‐pressure condensation as liquefaction method was also assessed. Through experimental investigations and VLE calculations, preservation of the composition of the produced liquid sample during condensation was studied. We conclude that under optimized conditions, validation, and calibration measurements of optical sensors can be performed on condensed liquids, which, however, needs further confirmation.