Premium
Efficient capture of CO 2 from flue gas at high temperature by tunable polyamine‐based hybrid ionic liquids
Author(s) -
Shi Guiling,
Zhao Hongqin,
Chen Kaihong,
Lin Wenjun,
Li Haoran,
Wang Congmin
Publication year - 2020
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.16779
Subject(s) - ionic liquid , flue gas , chemistry , polyamine , absorption (acoustics) , chemical engineering , lithium (medication) , ionic bonding , enthalpy , organic chemistry , materials science , ion , thermodynamics , catalysis , medicine , biochemistry , physics , engineering , composite material , endocrinology
For an ideal absorbent for CO 2 capture from flue gas, there are some key features including easy preparation, high stability, low absorption enthalpy, high capacity at high temperature and excellent reversibility. Herein, several polyamine‐functionalized ionic liquids (ILs) were easily prepared from cheap polyamines and lithium salts, which exhibited significantly improved stability due to the presence of multisite coordinating interactions. The viscosity was reduced by introducing polyalcohol‐based ILs, leading to polyamine‐based hybrid ILs. Interestingly, these polyamine‐based hybrid ILs exhibited high CO 2 capacity (4.09 mmol/g, 0.1 bar) at high temperature (80°C) and excellent reversibility in the presence of H 2 O and O 2 , which is superior to many other good absorbents. Moreover, these ILs also showed good performance for CO 2 capture from stimulated air (2.10 mmol/g, 380 ppm). We believe that this method with easy preparation, low cost, high efficiency and excellent reversibility has a great potential in the industrial capture of CO 2 from flue gas.