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Mass‐transfer rate enhancement for CO 2 separation by ionic liquids: Theoretical study on the mechanism
Author(s) -
Xie Wenlong,
Ji Xiaoyan,
Feng Xin,
Lu Xiaohua
Publication year - 2015
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.14932
Subject(s) - microscale chemistry , mass transfer , desorption , membrane , diffusion , chemistry , chemical engineering , nanoscopic scale , ionic liquid , non equilibrium thermodynamics , ionic bonding , absorption (acoustics) , chemical physics , flux (metallurgy) , nanotechnology , thermodynamics , materials science , adsorption , chromatography , ion , organic chemistry , catalysis , physics , biochemistry , mathematics education , mathematics , engineering , composite material
To promote the development of ionic liquid (IL) immobilized sorbents and supported IL membranes (SILMs) for CO 2 separation, the kinetics of CO 2 absorption/desorption in IL immobilized sorbents was studied using a novel method based on nonequilibrium thermodynamics. It shows that the apparent chemical‐potential‐based mass‐transfer coefficients of CO 2 were in three regions with three‐order difference in magnitude for the IL‐film thicknesses in microscale, 100 nm‐scale, and 10 nm‐scale. Using a diffusion‐reaction theory, it is found that by tailoring the IL‐film thickness from microscale to nanoscale, the process was altered from diffusion‐control to reaction‐control, revealing the inherent mechanism for the dramatic rate enhancement. The extension to SILMs shows that the significant improvement of CO 2 flux can be obtained theoretically for the membranes with nanoscale IL‐films, which makes it feasible to implement CO 2 separation by ILs with low investment cost. © 2015 American Institute of Chemical Engineers AIChE J , 61: 4437–4444, 2015