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Between‐phase calibration modeling and transition analysis for phase‐based quality interpretation and prediction
Author(s) -
Zhao Chunhui,
Gao Furong,
Sun Youxian
Publication year - 2013
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.13790
Subject(s) - linear subspace , subspace topology , quality (philosophy) , interpretation (philosophy) , process (computing) , phase (matter) , computer science , calibration , data mining , biological system , algorithm , artificial intelligence , mathematics , statistics , chemistry , physics , geometry , organic chemistry , quantum mechanics , biology , programming language , operating system
The quality‐concerned between‐phase transition analysis is performed and an improved calibration modeling strategy is designed for quality prediction and interpretation in multiphase batch processes. From the between‐phase viewpoint, the quality‐related phase behaviors are decomposed and two subspaces are separated. In common subspace, the underlying quality‐relevant variation stays invariable between the neighboring phases, showing the common contribution to quality. The other part changes with the alternation of phases and has the different influences on quality interpretation, termed specific subspace here. Based on subspace separation, between‐phase transition regions are distinguished from steady phases. Different models are developed in steady phases and transition regions respectively for online quality prediction. Offline quality analyses are also conducted in two subspaces to explore the time cumulative effects. The proposed method gives an interesting insight into the phase behaviors and between‐phase transitions for quality prediction. The feasibility and performance of the proposed method are illustrated with a typical multiphase batch process. © 2012 American Institute of Chemical Engineers AIChE J, 59: 108–119, 2013