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Simulations of photodegradation of toluene and formaldehyde in a monolith reactor using computational fluid dynamics
Author(s) -
Chong Siewhui,
Wang Shaobin,
Tadé Moses,
Ang H. Ming,
Pareek Vishnu
Publication year - 2011
Publication title -
aiche journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.958
H-Index - 167
eISSN - 1547-5905
pISSN - 0001-1541
DOI - 10.1002/aic.12295
Subject(s) - monolith , photodegradation , porous medium , formaldehyde , toluene , absorption (acoustics) , porosity , light intensity , materials science , kinetics , chemical engineering , chemistry , photocatalysis , mechanics , catalysis , optics , composite material , engineering , physics , quantum mechanics , biochemistry , organic chemistry
In this study, simulations were conducted on a monolith reactor for the photodegradation of toluene and formaldehyde. The monoliths in the reactor were treated as porous zones and the photocatalytic oxidation occurring on the monolith surfaces was modeled using Langmuir–Hinshelwood kinetics. A discrete ordinates model was used to simulate the light intensity with a novel approach, which involved an adjustable parameter—the absorption coefficient of the channel wall, for modeling the local light intensity across the porous media. The advantage of this approach was that despite its simplicity, it was able to capture and visualize the local light profile across the monolith channels and to integrate it into the reaction kinetics. Although it required a trial‐and‐error to determine the correct value of the channel wall absorption coefficient, the proposed model achieved a reasonable agreement between the simulation results and published experimental data. © 2010 American Institute of Chemical Engineers AIChE J, 2011