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Perovskite Solar Cells with Carbon‐Based Electrodes – Quantification of Losses and Strategies to Overcome Them
Author(s) -
Bogachuk Dmitry,
Yang Bowen,
Suo Jiajia,
Martineau David,
Verma Anand,
Narbey Stephanie,
Anaya Miguel,
Frohna Kyle,
Doherty Tiarnan,
Müller David,
Herterich Jan P.,
Zouhair Salma,
Hagfeldt Anders,
Stranks Samuel D.,
Würfel Uli,
Hinsch Andreas,
Wagner Lukas
Publication year - 2022
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.202103128
Subject(s) - materials science , perovskite (structure) , optoelectronics , photovoltaics , energy conversion efficiency , electrode , absorption (acoustics) , perovskite solar cell , band gap , carbon fibers , charge carrier , photovoltaic system , open circuit voltage , grain boundary , grain size , solar cell , voltage , chemical engineering , composite material , ecology , chemistry , physics , microstructure , quantum mechanics , composite number , engineering , biology
Carbon‐based electrodes represent a promising approach to improve stability and up‐scalability of perovskite photovoltaics. The temperature at which these contacts are processed defines the absorber grain size of the perovskite solar cell: in cells with low‐temperature carbon‐based electrodes (L‐CPSCs), layer‐by‐layer deposition is possible, allowing perovskite crystals to be large (>100 nm), while in cells with high‐temperature carbon‐based contacts (H‐CPSCs), crystals are constrained to 10–20 nm in size. To enhance the power conversion efficiency of these devices, the main loss mechanisms are identified for both systems. Measurements of charge carrier lifetime, quasi‐Fermi level splitting (QFLS) and light‐intensity‐dependent behavior, supported by numerical simulations, clearly demonstrate that H‐CPSCs strongly suffer from non‐radiative losses in the perovskite absorber, primarily due to numerous grain boundaries. In contrast, large crystals of L‐CPSCs provide a long carrier lifetime (1.8 µs) and exceptionally high QFLS of 1.21 eV for an absorber bandgap of 1.6 eV. These favorable characteristics explain the remarkable open‐circuit voltage of over 1.1 V in hole‐selective layer‐free L‐CPSCs. However, the low photon absorption and poor charge transport in these cells limit their potential. Finally, effective strategies are provided to reduce non‐radiative losses in H‐CPSCs, transport losses in L‐CPSCs, and to improve photon management in both cell types.