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Enabling High Efficiency of Hydrocarbon‐Solvent Processed Organic Solar Cells through Balanced Charge Generation and Non‐Radiative Loss
Author(s) -
Fan Baobing,
Lin Francis,
Oh Jiyeon,
Fu Huiting,
Gao Wei,
Fan Qunping,
Zhu Zonglong,
Li Wen Jung,
Li Ning,
Ying Lei,
Huang Fei,
Yang Changduk,
Jen Alex K.Y.
Publication year - 2021
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.202101768
Subject(s) - solubility , materials science , solvent , organic solar cell , energy conversion efficiency , radiative transfer , organic semiconductor , hydrocarbon , chemical engineering , acceptor , process engineering , solar cell , organic chemistry , optoelectronics , chemistry , polymer , physics , quantum mechanics , engineering , composite material , condensed matter physics
Using non‐halogenated solvents to process organic solar cells is preferable because they are less harmful to human health. However, it is challenging to mitigate the delicate trade‐offs between solubility and pre‐aggregation of organic semiconductors to maintain similar high device efficiencies as those processed by chlorinated solvents. The need for rigorous control of the kinetics between processing temperature and delay time inevitably complicates device processing for achieving reproducible performance. Herein, the authors develop a facile method to achieve proper solubility and pre‐aggregation in non‐halogenated solvents by selecting suitable donor/acceptor materials and subtle tuning of solvent compositions. This results in films with a high degree of ordering and suitably sized phase separation. Solar cells derived from this process can achieve a high power conversion efficiency up to 18%, which is the highest value reported for non‐halogenated solvent processed devices. This impressive result is achieved through synergistically reduced non‐radiative loss and enhanced charge generation.