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Architecting Amorphous Vanadium Oxide/MXene Nanohybrid via Tunable Anodic Oxidation for High‐Performance Sodium‐Ion Batteries
Author(s) -
Zhang Wang,
Peng Jian,
Hua Weibo,
Liu Ying,
Wang Jinsong,
Liang Yaru,
Lai Weihong,
Jiang Yue,
Huang Yang,
Zhang Wei,
Yang Huiling,
Yang Yingguo,
Li Lina,
Liu Zhenjie,
Wang Lei,
Chou ShuLei
Publication year - 2021
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.202100757
Subject(s) - materials science , amorphous solid , vanadium , anode , electrochemistry , raman spectroscopy , vanadium oxide , chemical engineering , mxenes , electrode , nanotechnology , chemistry , crystallography , physics , optics , metallurgy , engineering
Structural engineering and creating atomic disorder in electrodes are promising strategies for highly efficient and rapid charge storage in advanced batteries. Herein, a nanohybrid architecture is presented with amorphous vanadium oxide conformally coated on layered V 2 C MXene ( a ‐VO x /V 2 C) via tunable anodic oxidation, which exhibits a high reversible capacity of 307 mAh g –1 at 50 mA g –1 , decent rate capability with capacity up to 96 mAh g –1 at 2000 mA g –1 , and good cycling stability as a cathode for sodium‐ion batteries. The a‐ VO x layer enables reversible and fast Na + insertion/extraction by providing sufficient vacancies and open pathways in the amorphous framework, unlike the irreversible phase transition in its crystalline counterpart, while layered V 2 C MXene offers abundant electron/ion transfer channels, which are joined together to boost the electrochemical performance. Notably the improved reversibility and structural superiority of the a ‐VO x /V 2 C nanohybrid are clearly revealed by in situ Raman, in situ transmission electron microscopy, in situ synchrotron X‐ray absorption spectroscopy, and density functional theory calculations, demonstrating a reversible V–O vibration and valence oscillation between V 4+ and V 5+ in the disordered framework, with robust structural stability and unobstructed Na + diffusion. This work provides a meaningful reference for the elaborate design of MXene‐based nanostructured electrodes toward advanced rechargeable batteries.