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Asymmetric Acceptors Enabling Organic Solar Cells to Achieve an over 17% Efficiency: Conformation Effects on Regulating Molecular Properties and Suppressing Nonradiative Energy Loss
Author(s) -
Gao Wei,
Fu Huiting,
Li Yuxiang,
Lin Francis,
Sun Rui,
Wu Ziang,
Wu Xin,
Zhong Cheng,
Min Jie,
Luo Jingdong,
Woo Han Young,
Zhu Zonglong,
Jen Alex K.Y.
Publication year - 2021
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.202003177
Subject(s) - materials science , organic solar cell , acceptor , thiophene , ternary operation , energy conversion efficiency , side chain , small molecule , work (physics) , photovoltaic system , chemical physics , optoelectronics , polymer , organic chemistry , chemistry , thermodynamics , ecology , biochemistry , physics , biology , computer science , composite material , programming language , condensed matter physics
Y6, as a state‐of‐the‐art nonfullerene acceptor (NFA), is extensively optimized by modifying its side chains and terminal groups. However, the conformation effects on molecular properties and photovoltaic performance of Y6 and its derivatives have not yet been systematically studied. Herein, three Y6 analogs, namely, BP4T‐4F, BP5T‐4F, and ABP4T‐4F, are designed and synthesized. Owing to the asymmetric molecular design strategies, three representative molecular conformations for Y6‐type NFAs are obtained through regulating the lateral thiophene orientation of the fused core. It is found that conformation adjustment imposes comprehensive effects on the molecular properties in neat and blend films of these NFAs. As a result, organic solar cells (OSCs) fabricated with PM6:BP4T‐4F, PM6:BP5T‐4F, and PM6:ABP4T‐4F show high power conversion efficiency of 17.1%, 16.7%, and 15.2%, respectively. Interestingly, these NFAs with different conformations also show reduced energy loss ( E loss ) in devices via gradually suppressed nonradiative E loss . Moreover, by employing a selenium‐containing analog, CH1007, as the complementary third component, ternary OSCs based on PM6:BP5T‐4F:CH1007 (1:1.02:0.18) achieve a 17.2% efficiency. This work helps shed light on engineering the molecular conformation of NFAs to achieve high efficiency OSCs with reduced voltage loss.