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Periodic Porous 3D Electrodes Mitigate Gas Bubble Traffic during Alkaline Water Electrolysis at High Current Densities
Author(s) -
Kou Tianyi,
Wang Shanwen,
Shi Rongpei,
Zhang Tao,
Chiovoloni Samuel,
Lu Jennifer Q.,
Chen Wen,
Worsley Marcus A.,
Wood Brandon C.,
Baker Sarah E.,
Duoss Eric B.,
Wu Rui,
Zhu Cheng,
Li Yat
Publication year - 2020
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.202002955
Subject(s) - materials science , electrolyte , electrode , bubble , electrolysis , current density , alkaline water electrolysis , porosity , hydrogen , chemical engineering , electrolysis of water , coalescence (physics) , current (fluid) , nanotechnology , composite material , chemistry , thermodynamics , mechanics , physics , organic chemistry , quantum mechanics , astrobiology , engineering
Alkaline water electrolysis at high current densities is plagued by gas bubble generation and trapping in stochastic porous electrodes (e.g., Ni foams), which causes a significant reduction in the number of electrolyte accessible catalyst active sites. Here, 3D printed Ni (3DPNi) electrodes with highly controlled, periodic structures are reported that suppress gas bubble coalescence, jamming, and trapping and, hence, result in rapid bubble release. The 3DPNi electrodes decorated with carbon‐doped NiO achieve a high current density of 1000 mA cm −2 in 1.0 m KOH electrolyte at hydrogen evolution reaction and oxygen evolution reaction overpotentials of 245 and 425 mV, respectively. This work demonstrates a new approach to the deterministic design of 3D electrodes to facilitate rapid bubble transport and release to enhance the total electrode catalytic activity at commercially relevant current densities.