Premium
Visualization of Light Elements using 4D STEM: The Layered‐to‐Rock Salt Phase Transition in LiNiO 2 Cathode Material
Author(s) -
Ahmed Shamail,
Bianchini Matteo,
Pokle Anuj,
Munde Manveer Singh,
Hartmann Pascal,
Brezesinski Torsten,
Beyer Andreas,
Janek Jürgen,
Volz Kerstin
Publication year - 2020
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.202001026
Subject(s) - materials science , scanning transmission electron microscopy , lithium (medication) , atomic units , cathode , phase (matter) , oxide , phase transition , ion , diffraction , chemical physics , nanotechnology , transmission electron microscopy , optics , condensed matter physics , metallurgy , chemistry , medicine , physics , organic chemistry , quantum mechanics , endocrinology
Abstract The layered oxide LiNiO 2 (LNO) has been extensively investigated as a cathode active material for lithium‐ion batteries. Despite LNO's high gravimetric capacity, instability issues hinder its commercialization. It suffers from capacity loss during electrochemical cycling and is difficult to synthesize without defects. This is related to poor structural stability, leading to decomposition into the parent rock‐salt‐type oxide. In order to understand such phase transformations and to develop measures to inhibit them, the development of techniques able to image all atoms is crucial. In this study, the use of a fast, pixelated detector and 4D imaging in scanning transmission electron microscopy are explored to tackle this challenge. Selecting specific angular regions in the diffraction patterns and calculating virtual annular bright‐field images significantly enhances the contrast of the lithium atoms, such that all atoms are visible even in realistic samples. The developed technique is applied to image the layered‐to‐rock salt phase transition region. The data show that in this region, nickel atoms are in tetrahedral positions and the oxygen atoms are asymmetrically distributed. Taken together, the results shed light on the phase transformation mechanism at the atomic scale and can guide future research toward stabilizing LNO.