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Enhanced Potassium Ion Battery by Inducing Interlayer Anionic Ligands in MoS 1.5 Se 0.5 Nanosheets with Exploration of the Mechanism
Author(s) -
Fan HaiNing,
Wang XingYong,
Yu HaiBo,
Gu QinFen,
Chen ShanLiang,
Liu Zheng,
Chen XiaoHua,
Luo WenBin,
Liu HuaKun
Publication year - 2020
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201904162
Subject(s) - materials science , potassium , diffusion , ion , diffusion barrier , battery (electricity) , density functional theory , conductivity , chemical engineering , synchrotron , nanotechnology , chemistry , computational chemistry , organic chemistry , thermodynamics , power (physics) , physics , engineering , metallurgy , layer (electronics) , nuclear physics
The strategy of inducing interlayer anionic ligands in 2D MoS 1.5 Se 0.5 nanosheets is employed to consolidate the interlayer band gap and optimize the electronic structure for the potassium ion battery. It combines complementary advantages from two kinds of anionic ligands with high conductivity and good affinity with potassium ions. The potassium ion diffusion rate is accelerated as well by an optimized lower energy barrier for ion diffusion pathways, with the formation of highly reversible KMo 3 Se 3 crystal other than K 0.4 MoS 2 /K 2 MoS 4, which encounters a much slower electro/ion diffusion rate upon discharging. These advances deliver enhanced potassium storage properties with excellent cycling stability, with retained specific capacity of 531.6 mAh g −1 at a current density of 200 mA g −1 even after 1000 cycles, and high rate capability with specific capacity of 270.1 mAh g −1 at 5 A g −1 . The insertion and conversion mechanism are also elucidated by a combination of density functional theory computations and in situ synchrotron measurements.