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The Role of Cation Vacancies in Electrode Materials for Enhanced Electrochemical Energy Storage: Synthesis, Advanced Characterization, and Fundamentals
Author(s) -
Gao Peng,
Chen Zhen,
Gong Yuxuan,
Zhang Rui,
Liu Hui,
Tang Pei,
Chen Xiaohua,
Passerini Stefano,
Liu Jilei
Publication year - 2020
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201903780
Subject(s) - materials science , electrochemistry , mxenes , energy storage , nanotechnology , electrochemical energy storage , electrochemical energy conversion , transition metal , electrode , chemical physics , supercapacitor , chemistry , catalysis , thermodynamics , power (physics) , physics , biochemistry
The incorporation of atomic scale defects, such as cation vacancies, in electrode materials is considered an effective strategy to improve their electrochemical energy storage performance. In fact, cation vacancies can effectively modulate the electronic properties of host materials, thus promoting charge transfer and redox reaction kinetics. Such defects can also serve as extra host sites for inserted proton or alkali cations, facilitating the ion diffusion upon electrochemical cycling. Altogether, these features may contribute to improved electrochemical performance. In this review, the latest progress in cation vacancies‐based electrochemical energy storage materials, covering the synthetic approaches to incorporate cation vacancies and the advanced techniques to characterize such vacancies and identify their fundamental role, are provided from the chemical and materials point of view. The key challenges and future opportunities for cation vacancies‐based electrochemical energy storage materials are also discussed, particularly focusing on cation‐deficient transition metal oxides (TMOs), but also including newly emerging materials such as transition metal carbides (MXenes).