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Thermally Durable Nonfullerene Acceptor with Nonplanar Conjugated Backbone for High‐Performance Organic Solar Cells
Author(s) -
Cho Hye Won,
An Na Gyeong,
Park Song Yi,
Shin Yun Seop,
Lee Woojin,
Kim Jin Young,
Song Suhee
Publication year - 2020
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201903585
Subject(s) - materials science , conjugated system , acceptor , organic solar cell , band gap , polymer solar cell , energy conversion efficiency , open circuit voltage , absorption (acoustics) , electron acceptor , polymer , optoelectronics , side chain , photochemistry , voltage , chemistry , physics , quantum mechanics , composite material , condensed matter physics
A nonfullerene acceptor (NFA) with acceptor–donor–acceptor (A–D–A) architecture, i‐IEICO‐2F, based on 4,9‐dihydro‐ s ‐indaceno[1,2‐ b :5,6‐ b ′]dithiophene as an electron‐donating core and 2‐(6‐fluoro‐2,3‐dihydro‐3‐oxo‐1 H ‐inden‐1‐ylidene)‐propanedinitrile as electron‐withdrawing end groups, is designed and synthesized. i‐IEICO‐2F has a twist structure in the main conjugated chain, which causes blueshifted absorption and leads to harmonious absorption with a high bandgap donor. The bandgap of i‐IEICO‐2F compliments the bandgap of suitable wide bandgap donor polymers such as J52, leading to complete light absorption throughout the visible spectrum. Devices based on i‐IEICO‐2F exhibit optimized photovoltaic performance including an open‐circuit voltage of 0.93 V, a short‐circuit current density of 16.61 mA cm −2 , and a fill factor of 73%, and result in a power conversion efficiency (PCE) of 11.28%. The i‐IEICO‐2F‐based devices reach PCEs of >11% without using any additives or post‐treatments. Devices are found to be thermally stable and maintain 44% of their initial PCE after 184.5 h of continuous thermal annealing (TA) treatment at 150 °C. Based on UV, atomic force microscopy (AFM), and grazing incidence wide angle X‐ray scattering (GIWAXS) results, i‐IEICO‐2F devices show almost identical morphology and molecular orientation throughout the TA treatment and excellent stability compared to other IEICO derivatives.