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In Situ Generation of Artificial Solid‐Electrolyte Interphases on 3D Conducting Scaffolds for High‐Performance Lithium‐Metal Anodes
Author(s) -
Zhai Pengbo,
Wei Yi,
Xiao Jing,
Liu Wei,
Zuo Jinghan,
Gu Xiaokang,
Yang Weiwei,
Cui Shiqiang,
Li Bin,
Yang Shubin,
Gong Yongji
Publication year - 2020
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201903339
Subject(s) - materials science , anode , electrolyte , current collector , lithium (medication) , chemical engineering , cathode , electrode , layer (electronics) , passivation , current density , lithium metal , foil method , nanotechnology , composite material , chemistry , medicine , engineering , endocrinology , physics , quantum mechanics
Rational structure design of the current collector along with further engineering of the solid‐electrolyte interphases (SEI) layer is one of the most promising strategies to achieve uniform Li deposition and inhibit uncontrolled growth of Li dendrites. Here, a Li 2 S layer as an artificial SEI with high compositional uniformity and high lithium ion conductivity is in situ generated on the surface of the 3D porous Cu current collector to regulate homogeneous Li plating/stripping. Both simulations and experiments demonstrate that the Li 2 S protective layer can passivate the porous Cu skeleton and balance the transport rate of lithium ions and electrons, thereby alleviating the agglomerated Li deposition at the top of the electrode or at the defect area of the SEI layer. As a result, the modified current collector exhibits long‐term cycling of 500 cycles at 1 mA cm −2 and stable electrodeposition capabilities of 4 mAh cm −2 at an ultrahigh current density of 4 mA cm −2 . Furthermore, full batteries (LiFePO 4 as cathode) paired with this designed 3D anode with only ≈200% extra lithium show superior stability and rate performance than the batteries paired with lithium foil (≈3000% extra lithium). These explorations provide new strategies for developing high‐performance Li metal anodes.