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Boosting the Stable Na Storage Performance in 1D Oxysulfide
Author(s) -
Xu Jijian,
He Jianqiao,
Ding Wei,
Hong Zhanglian,
Huang Fuqiang
Publication year - 2019
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201900170
Subject(s) - faraday efficiency , anode , materials science , boosting (machine learning) , crystal structure , ion , conductivity , chemical engineering , electrode , nanotechnology , crystallography , chemistry , computer science , organic chemistry , machine learning , engineering
Exploring new structure prototypes and phases by material design, especially anode materials, is essential to develop high‐performance Na‐ion batteries. This study proposes a new anode, Na 2 Cu 2.09 O 0.50 S 2 , with a 1D crystal structure and outstanding Na storage performance. In view of the crystal structure of Na 2 Cu 2.09 O 0.50 S 2 , [Cu 4 S 4 ] chains act as electrically conducting units enabling conductivity as high as 0.5 S cm −1 . The residual Na 4 [CuO] chains act as ionically conducting units forming rich channels for the fast conduction of Na ions as well as maintaining the structural stability even after Na ion extraction. Additional ball milling on the as‐prepared Na 2 Cu 2.09 O 0.50 S 2 significantly decreases its grain size, achieving a capacity of 588 mA h g −1 with a high initial Coulombic efficiency of 93% at 0.2 A g −1 . Moreover, the Na 2 Cu 2.09 O 0.50 S 2 anode demonstrates outstanding rate capability (408 mA h g −1 at 2 A g −1 ) and extending cyclic performance (82% of capacity retention after 400 cycles). The general structural design idea based on functional units may offer a new avenue to new electrode materials.